Board Thread:Pokémon Help/@comment-30804097-20170511162717/@comment-31796688-20170512175024

No. According to bulbapedia:

"Successfully using Protect, Detect, Endure, Wide Guard, Quick Guard, Spiky Shield, or King's Shield consecutively now divides the chance of success of Protect, Detect, Endure, Spiky Shield, and King's Shield by 3 for each consecutive use, with a minimum (1/3)^6 (1/729 or ~0.1%) chance.[6]"