Steam Chamber

Steam Chamber is a secret basement that the player can enter in Brimber City, which first time the player enters the city, the entrance is blocked by a gigantic rock that cannot be destroyed until the player gets to Port Decca and finishes a small quest. Mythical Pokémon Volcanion, which is the final Legendary or Mythical Pokémon to be related to volcano after Groudon and Heatran, resides in this secret basement.

Description
Once the player enters, climb down flights of stairs until the player reaches the main area. The area has full of cracks on the walls and on the floor with steam coming out of it, red crystals spread everywhere, pillars scattered around, and a gigantic pool of lava in a small chasm with a broken bridge as the player continues walking.

There is a door up ahead which the player is able to see Volcanion in the distance. To get over there, the player must find a small opening to the left near the bridge and follow the path down until the player reaches the other side. There is water seen around the area as well when the player is following the path. As soon as the player gets to the other side, the player will be able to enter through the door and encounter Volcanion.

Catching Volcanion
The player can see Volcanion from the opposite side of the chasm and must follow a long path to get to it. Once the player clicks on Volcanion, it will give out a loud roar, and the battle will commence. Players only have 1 chance to catch it, so save beforehand and turn off the Autosave function. As Volcanion is very hard to catch and shows up deep in a volcano, it is recommended to stock up on Dusk Balls in Poké Ball Emporium, Anthian City - Shopping District beforehand.

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Trivia

 * There is water inside the volcano, which defies logic. However, it is likely that this represents how Volcanion can use both fire and water to its advantage.